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Publication detail

Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry
Year: 2009
Type of publication: článek v odborném periodiku
Name of source: Beilstein Journal of Organic Chemistry
Publisher name: Beilstein-Institut
Place: Frankfurt am Main
Page from-to: 1-5
Titles:
Language Name Abstract Keywords
cze Přehledné metody přípravy π-konjugovaných vazeb jako stavebních kamenů pro modulární chemii Jsou popsány jednoduché, přímočaré postupy pro přípravu rozšířených π-konjugovaných vazeb.
eng Convenient methods for preparing π-conjugated linkers as building blocks for modular chemistry Simple, straightforward and optimized procedures for preparing extended π-conjugated linkers are described. Either unsubstituted or 4-donor substituted π-linkers bearing a styryl, biphenyl, phenylethenylphenyl, and phenylethynylphenyl π-conjugated backbone are functionalized with boronic pinacol esters as well as with terminal acetylene moieties allowing their further use as building blocks in Suzuki-Miyaura or Sonogashira coupling reactions. boronic acid;donor/acceptor;linker;Sonogashira reaction;property tuning;push- pull;Suzuki-Miyaura reaction